Domain Size of Phase-Separated NaxCoO2 as Investigated by X-Ray Microdiffraction

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Domain Size of Phase-Separated NaxCoO2 as Investigated by X-Ray Microdiffraction

O3-NaCoO2 is a promising cathode material for sodium ion secondary batteries (SIBs). NaxCoO2 shows phase separation (PS) into the O3 and O′3 phases in the Na concentration range of 0.89 6 x 6 0.99. In order to estimate the domain size (r) in the two-phase region, we performed X-ray microdiffraction (XRMD) of thin films of NaxCoO2 at x = 0.97 and ∼1. We found that r (≈400 nm) of the O′3 domain i...

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ژورنال

عنوان ژورنال: Batteries

سال: 2017

ISSN: 2313-0105

DOI: 10.3390/batteries3010005